|本期目录/Table of Contents|

[1]孙 奎,李 哲,陈 娟*.微量级氯离子电极传感器的研究[J].工业仪表与自动化装置,2018,(05):13-16.[doi:1000-0682(2018)05-0000-00]
 SUN Kui,LI Zhe,CHEN Juan*.Study on micro level chloride ion electrode sensor[J].Industrial Instrumentation & Automation,2018,(05):13-16.[doi:1000-0682(2018)05-0000-00]
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微量级氯离子电极传感器的研究

《工业仪表与自动化装置》[ISSN:1000-0682/CN:61-1121/TH]

卷:
期数:
2018年05期
页码:
13-16
栏目:
出版日期:
2018-10-15

文章信息/Info

Title:
Study on micro level chloride ion electrode sensor
作者:
孙 奎李 哲陈 娟*
北京化工大学 信息科学与技术学院,北京 100029
Author(s):
SUN Kui LI Zhe CHEN Juan*
College of Information Science & Technology, Beijing University of Chemical Technology, Beijing 100029, China
关键词:
氯离子电极pH温度阴离子
Keywords:
chlorine ion electrode pH temperature anions
分类号:
TH832
DOI:
1000-0682(2018)05-0000-00
文献标志码:
A
摘要:
该文以聚3,4-乙烯二氧噻吩作为氯离子电极的导电接触层,制备了全固态氯离子选择性电极。通过电化学分析方法,得出电极的检测浓度能达到10-4.6 mol/L,研究pH、常见阴离子和温度对电极检测干扰的影响。实验结果表明:所研制的氯离子电极适用于pH范围在5~8之间,待测溶液中应避免卤族或与卤族元素相近的阴离子的存在,同时温度对检测微量级浓度氯离子溶液影响较大。在微量级浓度测量时应在恒温条件下检测。
Abstract:
In this paper, poly(3,4-Ethylenedioxythiophene) is used as the solid-state conductive contact layer of the chloride ion electrode, all solid-state chlorine ion selective electrodes were made by 3,4-Ethylenedioxythiophene. By the electrochemical analysis method, the detection concentration of the electrode can reach 10-4.6 mol/L, study the influence of pH, common anions and temperature on the interference of the electrode detection.The experimental results show that the chloride ion electrode developed in this paper is suitable for the rang of pH is 5~8, avoid halogen or similar to the halogen anions should be the existence of the text solution, the temperature has a great influence on the detection of micro level concentration of chloride ion solution. In the micro level concentration measurement, it should be detected at constant temperature.

参考文献/References:

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[7] Mohammed M Rahman, Sher Bahadar Khan, George Gruner,et al.Chloride ion sensors based on low- dimensional-MnO2–Co3O4 nanoparticles fabricated glassy carbon electrodes by simple I–V technique[J]. Electrochimica Acta,2013(103):143–150.
[8] 李雅卓,王广伟,金建余,等.基于两电极体系脉冲计时电流法的离子选择性检测[J].传感技术学报,2014, 27(01):12-16.
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备注/Memo

备注/Memo:
收稿日期:2018-03-15
基金项目:国家自然科学基金(61771034)
作者简介:孙奎(1990),男,硕士研究生,研究方向为智能水质检测。通讯作者:陈娟,女,教授,主要研究方向为先进控制算法研究,智能水质检测技术研究。
更新日期/Last Update: 2018-10-15